When you begin the game it will start in Practice mode. Press Start and go to the "Practice" settings to change your players. Change your player to any superstar. Go back to Practice mode to view a video of their go-to-move.
Chris Paul has a second go-to-move other than his run and throw up shot, which is almost the same go-to-move as Derron Williams. Do the same as you would with Derron's go-to-move by pressing the Analog-stick LEFT or RIGHT + CIRCLE (Shoot).